Presentation
The second research topic concerns the design of sustainable materials used for example in the field of renewable energies (off-shore wind turbines) or for structures in marine environment. Particular attention is devoted to the development of new biobased polymer networks and composites such as bio-vitrimers, bio-hydrogels or cellulose-reinforced composites.
The understanding of the mechanics behind the durability of cross-linked coatings and composite materials must be supplemented by an end-of-life plan or integration into the circular economy through thermoset material recycling or shaping. Vitrimers embody these principles, combining the mechanical properties of thermosets in operation with the malleability of thermoplastics, which is necessary for recycling and self-repair. In the marine sector, interest is focused on epoxy or polyurethane vitrimers, whose chemistries have proven their durability. The network engineering implemented thanks to the selected chemistries is aimed at controlling the activation of dynamic covalent bonds as a function of temperature, mechanical stress and environment. Specifically, we develop expertise in fluorescence and Raman spectroscopies to investigate the kinetics of reversible covalent bonding with molecular and macromolecular dynamics.
Conferences and communications :
2024
- Serrano Stéphane, Berlioz Sophie, Hajjoul Houssam, Richaud Emmanuel, Carriere Pascal
Thermal degradation of aromatic amine cured epoxidized lindseed oil
Modification, Degradation, Stabilization of Polymers Society, Palermo (Italy), september 2024
- Serrano Stéphane, Berlioz Sophie, Hajjoul Houssam, Richaud Emmanuel, Carriere Pascal
High-performance, bio-based, tri-component vitrimer networks based on epoxydized vegetable oils: Control of the network synthesis and morphology
Biopol 2024, Coimbra (Portugal), July 2024
- Pascal Carriere
Fluorescence spectroscopy apply to thermoset networks characterizations: heterogeneities, ageing, dynamic covalent bonds
IMP-Days - Thermosets, Lyon (France), April 2024
- Serrano Stéphane, Berlioz Sophie, Hajjoul Houssam, Emmanuel Richaud, Pascal Carriere, Carriere Pascal
Applications de la spectroscopie de fluorescence pour le suivi de vieillissement thermo-oxydatif de réseau époxys
2ème conférence francophone VIP : vieillissement des polymères, Saint-Valery-en-Caux (France) june 2024
- Fahs Armand, Carriere Pascal
Vieillissement hydrolytique de vitrimères époxy-amine : rôle sur les relaxations de contraintes et l’autoréparation
2ème conférence francophone VIP : vieillissement des polymères, Saint-Valery-en-Caux (France), june 2024
2023
- Castro-Cabrera Isis ,Fahs Armand ,Berlioz Sophie, Carriere Pascal
Modeling Multiple Stress Relaxations behaviors of Dynamic Polymer Network near its Glass Transition Temperature
EUPOC2023 Dynamic Polymer Networks, Bertinoro (Italy), may 2023
- Pascal Carriere
Un outil performant pour l’analyse du vieillissement des interphases dans les matériaux composites: la spectroscopie de fluorescence
Polymères & composites, Toulouse (France) september 2023